Toray Industries has concluded a joint venture agreement with LG Chem under which LG Chem will invest $375 million in Toray Industries Hungary (THU), establishing LG Toray Hungary Battery Separator (LTHS), in which Toray and LG Chem will each hold a 50% interest. The new joint venture will use existing THU facilities to manufacture battery separator film for automotive batteries for sale to LG Group in Europe and the US.
LTHS will license the technologies to produce separators for LG Group batteries. The joint venture also aims to follow LG Group’s business model, which vertically integrates everything from battery materials through battery production. The Toray Group will continue to develop, manufacture and supply battery separator film and coating in Japan and Korea.
Battery supplier SES has released Apollo, a 107 Ah Li-metal battery for EVs.
The company also announced plans for its Shanghai Giga plant, a 300,000-square-foot facility that the company hopes will be capable of producing 1 GWh of batteries annually by 2023.
SES has addressed the dendrite safety problem associated with Li-metal batteries by coating lithium metal with a polymer coating and using a high-concentration electrolyte that suppresses the formation of dendrites.
Apollo can deliver 107 Ah, weighs 0.982 kg, and has specific energy of 417 Wh/kg and energy density of 935 Wh/L. Apollo demonstrated similarly high capacity and energy density when tested at 10-hour discharge, 3-hour discharge, and 1-hour discharge times at room temperature.
SES also introduced three development tracks. Hermes is a material development platform for developing Li-metal cells with lighter weight and higher energy density. Apollo is focused on developing large automotive cells, and Avatar is the company’s AI-powered safety software designed to monitor battery health.
“Batteries need to be capable of delivering high energy density over a wide range of temperature and power densities,” said Dr. Qichao Hu, CEO of SES. “A car needs to work in hot and cold environments, and perform seamlessly when driven fast or slowly. Solid-state batteries can never achieve this performance at the level of our hybrid Li-metal batteries.”
Spanish EVSE manufacturer Circontrol has added two new models to its Raption line of DC fast chargers: the Raption 150 Compact and the Raption 350 join the company’s popular Raption 100.
The two new chargers are intended for different types of sites. The Raption 350 is a high-power system requiring an electrical cabinet or a nearby medium-voltage transformer station, and is designed for EV charging stations and service roads. The Raption 150 Compact is designed to be installed roadside, or at shopping malls and other sites wishing to offer fast charging in a small space.
All Raption models feature a modular design. This allows modules to be shut down when vehicles require less power or to continue functioning if other modules fail. Charging power can be adjusted to suit the needs of each user, and can be scaled if required.
Both new models offer the option for two cars to charge simultaneously. The Raption 150 Compact can split its power to charge two vehicles at 75 kW, and the Raption 350 can offer up to 175 kW to each car.
“These systems will help develop a high-power EV charging infrastructure network, which will streamline the ultimate rollout of EVs in our country [Spain],” said Circontrol Managing Director Joan Hinojo. “There will no longer be any question about EVs being able to travel long distances. The slow chargers we may have at home or at places where we spend the majority of our time are necessary, and good for batteries, but there is no denying that the [high-power] systems on the country’s main roadways are essential.”
By: Peter Klaerner, senior manager for Wedge Bond Systems Engineering, Kulicke & Soffa
Wire and ribbon bonding have traditionally been the methods of choice for creating reliable interconnects in the electronics industry. The progress in electric vehicle production has created the need for better, more reliable interconnects that can be scaled to high-volume manufacturing. It is no surprise therefore that leading automotive manufacturers in the electric vehicle space have turned to wire bonding for their interconnect needs. Such interconnects must be able to handle extreme temperature ranges in addition to shock and vibration conditions over increasingly longer lifetimes. There are several areas of application for interconnects in electric cars. Some of the applications include: battery cell-to-cell connections; battery cell-to-busbar connections; battery management system (BMS) interconnects; and power module interconnects in the electric car drive train.
A leading electric manufacturer claims that their previous battery generation was designed to last up to 500,000 miles of service and their current generation of batteries is targeted to last up to 1,000,000 miles of service. While only limited real-world data is available due to the somewhat nascent proliferation of electric vehicles, long-term data available so far has shown that those claims may be credible. In addition to the battery chemistry that holds the electric charge, the interconnect elements between battery cells and sections are components that see stress over the product lifetime. Between the multiple interconnect methods being used in battery interconnects (see Figure 1), wire bonding is the method with the most real-world data available demonstrating its reliability.
Figure 1: Common battery cell interconnects by cell type
What are the advantages of wire bonding making it a preferred method of interconnect formation in the electric car industry?
Advantages
Quasi room-temperature process
The wedge wire bonding processes do not
require external thermal energy. In contrast to other methods like resistance
welding, soldering or laser welding, the substrate to be bonded does not need
to be heated nor does the wedge bond process induce heating. During the wedge
bonding process, very localized heating occurs only for a very short time due
to the micro-friction occurring between the bond interfaces. This is a great
advantage when forming interconnects in heat sensitive battery cells or
integrated circuits.
Flexibility
Wire interconnects can span considerable
distances and height differences between interconnect points. Product
iterations leading to changes in both distances or heights can be easily
accommodated with a simple software adjustment – no new costly hardware has to
be manufactured. This flexibility also enables different product configurations
to be processed on the same bonder equipment requiring only a product-specific
process program to be loaded.
Ambient and product-related thermal
stresses can be accommodated with stress relief loops between the interconnect
points. Wire interconnect processes have been developed between 18-micron wire
diameter on the low side, and up to 600-micron wire diameter on the high side. Suitable
wire sizes can be chosen to match resistance and conductivity requirements. For
fine-tuning of exact resistivity or impedance, as is sometimes required in
electronics processes, the loop shape can be dynamically adapted to changes in
bond locations for desired resistivity or impedance matching. Ribbon bonding processes
– typically used to enable higher current transfer due to their higher cross
sections – have also been developed to cover a large range of sizes.
This flexibility enables cost savings
during the pre-production phase, and also during the production phase.
In-process monitoring
During the wire bond process, a number of
electrical and mechanical signals are being captured in real-time. While the
bond process is taking place, this allows for an immediate evaluation of the
bond conditions and a judgment of bond quality. With modern data analysis tools,
it is possible to classify and match signatures of common failure modes such as
contamination or misplaced bonds and store questionable bonds for later
post-bond review. Connecting and storing the bond data with product serial
codes it is possible to have full traceability back to each individual bond.
Mechanical process assurance
Wire bonding offers the ability to perform
a mechanical pull test in-situ. In this non-destructive test, a pre-defined
pull force is applied to test the bond strength after each bond is completed. Pull
testing detects infant mortality failures of weak or non-stick bonds. Similar
to the bond process data, pull test results are immediately available and can
be stored for full traceability.
Ability to re-work
Wire bonding offers the ability to remove
weak or failed wires on an individual wire level and attempt rework. The
ability to rework offers a unique advantage compared to other interconnect methods
which only have a singular chance of success.
Proven technology & reliability
Wire bonding as an electrical interconnect
technology has been used since at least the 1960s and has continuously been
improved. As explained earlier in this article, reliability in electronic
components has been demonstrated, and more recent evidence confirms that wire
bonding is suitable also for the extended shock and vibration demands placed on
it for battery cell applicationsiii.
Established supply chain for both equipment and consumables
For large scale automotive production, a
stable supply chain for both equipment and also consumables (such as bonding
wire) is available with a global reach.
Fusing
As explained earlier, in a typical wire bond application the interconnect is designed to endure harsh environmental conditions. There is however a use-case in which there is a designed and desired failure point of the wire bond: when an un-intended overcurrent condition occurs. U.S. Patent No. 7,671,565, assigned to Tesla, Inc., described it as follows: “A system and method links batteries in parallel to conductors using wire bonds that act as fuses in the event of an overcurrent condition in a battery.” The wire bond can be specifically tuned to the required fusing characteristics by selecting a suitable wire size and loop length – both of which determine the resistivity of the interconnect.
Limitations
Of course, every process has some limitations. For wire bonding processes, exemplary limitations include:
Serial process of interconnection
Wire bonding is serial in nature in that
each bond has to be formed sequentially. The only method to parallelize work involves
multiple bond heads working on the same product at the same time. This adds
complexity to the equipment and often limits flexibility. If a product is very
repeatable in dimensions a multi-bond head approach can be executed. Such
equipment has been used, for example, in solar cell interconnects where the
bond locations are identical for each workpiece.
Contamination
Contamination at either bonding interface can
greatly affect the bond integrity. This applies to organic materials such as
hydrocarbons and non-organic materials such as oxidation and dust. Mild
contamination may be addressed with selective bond parameters, while severe
contamination typically requires a cleaning process. Particularly in the
prototyping stage of battery development packs, it is not uncommon to deal with
epoxy and other polymer residue caused for example by 3D printing during the
wire bonding stage. While this contamination is caused by outside factors it can
greatly influence the successful outcome of the wire bond process.
Requirement for a stable substrate surface
During the wire bonding process, ultrasonic energy is applied under pressure. The ultrasonic energy can cause harmonics that create resonance with the substrate surface. Excessive vibration of the substrate surface can negatively interact with the bond formation leading to weak or no-stick bonds. Therefore, a product design guideline used during the development process may include providing for a stable bond surface to ensure the highest success for the wire bond process. Particularly, battery cells tend to have a weak spot regarding vibration with the top cover of the battery cell having only support on its sides but none in the center (Figure 2).
Figure 2: Sketch of cross-section showing unsupported center of battery cell top cover
Requirements for accurate placement location
While requirements for accurate placement
location exist for all manufacturing processes, there are some unique
challenges in the realm of battery cell interconnects. Such applications
typically require that each cell be located at a known location so the bonder
can accurately place each bond. Usually, this task is aided by using machine
vision to locate reference marks on the product while each battery cell is
located relative to that reference mark. It can be appreciated that as product
dimensions grow there are stack-up tolerances during the battery module
assembly process that negatively affect cell location accuracy. While a more
precise assembly process can improve cell location accuracy it comes with the
drawback of significantly higher product cost which affects each module. Another
approach is to introduce more reference marks throughout the product to lessen
the effect of stack-up tolerances across a large area by sub-dividing the area
into small sections. Locating additional reference marks, however, requires
additional find time prior to the wire bonding process, thereby increasing the
overall cycle time. A brute force approach would be to use machine vision to
locate each individual cell prior to bonding. This cell locating operation can
be performed within the bonder but consumes an inordinate amount of time just
for locating each cell. Another approach would be to locate each cell before
the product enters the bonder with the drawback of having to transfer and
synchronize a large amount of data between various systems. In summary, the
solution to accurate cell placement comes at a significant cost and technical
complexity.
Suitable metallurgy combinations
Wire bonding performs best with a number of
suitable metallurgy combinations. Much research has been done to explore the
bondability of various material combinations and a number of well-performing
combinations have been identified. Typically mono-metallic bonds form the best
connections such as aluminum-to-aluminum or copper-to-copper. While dissimilar
metal combinations can be used the exact combination has to be evaluated as to
bondability. It is advantageous if battery module and cell designers take the
wire bonding process into consideration during the design cycle to achieve
optimum production robustness. In cases
where certain metallization is required that by itself wouldn’t lend itself
well to bonding, coatings can be
explored since wire bonding also works well on certain coated surfaces. This
article only gives a very high level overview – Kulicke & Soffa will be
happy to evaluate your specific application as to bondability.
Spreading beyond automotive
The success of wire bonding demonstrated in automotive battery applications has begun to spread to adjacent applications. Given the advantages wire bonding offers it is no wonder that wire bonding is now being utilized in applications such as energy storage, electric bikes, and motorcycles.
Kulicke & Soffa continues to provide innovative solution to create future possibilities.
